http://repositorio.unb.br/handle/10482/44373
Titre: | Numerical modeling and experimental assessment of sustainable woody biomass torrefaction via coupled TG-FTIR |
Auteur(s): | Silveira, Edgar Amaral Luz, Sandra Maria da Leão, Rosineide M. Rousset, Patrick Caldeira-Pires, Armando de Azevedo |
Assunto:: | Modelagem numérica Torrefação Biomassa |
Date de publication: | mar-2021 |
Editeur: | Elsevier |
Référence bibliographique: | SILVEIRA, Edgar A. et al. Numerical modeling and experimental assessment of sustainable woody biomass torrefaction via coupled TG-FTIR. Biomass and Bioenergy, v. 146, 105981, mar. 2021. DOI: https://doi.org/10.1016/j.biombioe.2021.105981. |
Abstract: | Torrefaction is an inert thermal process (up to 300 ◦C) that promotes changes in the chemical and physical properties of biomass, decreasing the time and energy required for biomass conversion. In this work, an online method - TG coupled with FTIR - and elemental analysis were applied to acquire data in order to perform an experimental and numerical thermal upgrading assessment of Eucalyptus grandis, and in turn study the torrefaction mechanism. A thermal sensitivity numerical model was employed to obtain two-step reaction kinetic rates and solid and volatile compositions. The FTIR results added new perceptions that correlate and validate the solid and volatile pseudo-component distribution, the solid elemental composition prediction, devolatilization, and solid HHV estimation. As a result, the 2D property mapping allowed for a qualitative and quantitative assessment of all torrefaction severities. The obtained kinetics and the response diagrams from the numerical results can provide valuable references for practical operations and reactor design. |
metadata.dc.description.unidade: | Faculdade UnB Gama (FGA) |
DOI: | https://doi.org/10.1016/j.biombioe.2021.105981 |
metadata.dc.relation.publisherversion: | https://www.sciencedirect.com/science/article/pii/S0961953421000180?via%3Dihub |
Collection(s) : | Artigos publicados em periódicos e afins |
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