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dc.contributor.authorCampos, Pablo Teles Aragão-
dc.contributor.authorLima, João Pedro Vieira-
dc.contributor.authorSilva, Daniele Renata de Queiroz-
dc.contributor.authorOliveira, Claudinei Fabiano de-
dc.contributor.authorDias, Sílvia Cláudia Loureiro-
dc.contributor.authorDias, José Alves-
dc.date.accessioned2022-04-12T15:58:25Z-
dc.date.available2022-04-12T15:58:25Z-
dc.date.issued2020-
dc.identifier.citationCAMPOS, Pablo Teles Aragão et al. Cerium–zirconium mixed oxide nanostructures for diesel soot oxidation: synthesis and effect of structure. RSC Advances, v. 10, p. 27428-27438, 2020. DOI: https://doi.org/10.1039/D0RA05130F. Disponível em: https://pubs.rsc.org/en/content/articlelanding/2020/ra/d0ra05130f. Acesso em: 12 abr. 2022.pt_BR
dc.identifier.urihttps://repositorio.unb.br/handle/10482/43380-
dc.language.isoInglêspt_BR
dc.publisherRoyal Society of Chemistrypt_BR
dc.rightsAcesso Abertopt_BR
dc.titleCerium–zirconium mixed oxide nanostructures for diesel soot oxidation : synthesis and effect of structurept_BR
dc.typeArtigopt_BR
dc.subject.keywordNanoestruturaspt_BR
dc.subject.keywordÓxido de zincopt_BR
dc.subject.keywordÓxido de cériopt_BR
dc.rights.license(CC BY)pt_BR
dc.identifier.doihttps://doi.org/10.1039/D0RA05130Fpt_BR
dc.description.abstract1Nanostructured materials have been used in several branches of science and technology. Particulate matter is one of the major air pollution concerns. In this work, nanorods and nanoparticles of Ce0.8Zr0.2O2 (CZ) mixed oxides were prepared by different routes, and the use of an organic template was evaluated in diesel soot oxidation. The catalysts were characterized by several techniques including structural analysis (XRD, TEM, N2 adsorption–desorption) and activity (TPR/MS, TPO/MS). A fast TPR/MS method is proposed to calculate hydrogen consumption that can be correlated to the oxygen storage capacity (OSC). It was demonstrated that CZ-nanorods with twice the amount of template in the syntheses (CZ-NRs-2X) were very active for soot oxidation with T50% at 351 °C, and CO2 and H2O were the only oxidation products from Printex®-U (Evonik). This catalyst, reported for the first time, was subjected to up to three cycles and it showed fair activity, proving that this morphology is one of the best mixed oxides of CZ for oxidation.pt_BR
dc.identifier.orcidhttps://orcid.org/0000-0002-3351-9226pt_BR
dc.identifier.orcidhttps://orcid.org/0000-0003-0042-0091pt_BR
dc.description.unidadeInstituto de Química (IQ)pt_BR
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