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dc.contributor.authorCosta, Maísa Borgespt_BR
dc.contributor.authorMartins, Marcos P.pt_BR
dc.contributor.authorAraújo, Hugo Clemente dept_BR
dc.contributor.authorResck, Inês Sabionipt_BR
dc.date.accessioned2019-01-02T13:52:01Z-
dc.date.available2019-01-02T13:52:01Z-
dc.date.issued2018pt_BR
dc.identifier.citationCOSTA, Maísa B. et al. Synthesis and expansion of bicyclic enol ether: a probable precursor for the synthesis of macrolide (±)-pyrenophorin. Journal of the Brazilian Chemical Society, São Paulo, v. 29, n. 1, p. 74-78, jan. 2018. DOI: http://dx.doi.org/10.21577/0103-5053.20170114. Disponível em: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532018000100074&lng=en&nrm=iso. Acesso em: 16 maio 2019.pt_BR
dc.identifier.urihttp://repositorio.unb.br/handle/10482/33450-
dc.description.abstractA convenient procedure for the synthesis and expansion of bicyclic rings has been developed for the production of probable precursors of non-racemic pyrenophorin, an antibiotic dilactone. The major highlight for this new synthetic methodology came from the use of a readily available reagent of easy manipulation, 9-oxabicyclo[3.3.1]nonane-2,6-diol, for the preparation of the bicyclic intermediate, which sequentially was subjected to oxidative cleavage with butyl nitrite resulted in an isomeric mixture, a dioximedilactone and diisoxazoledilactone.pt_BR
dc.language.isoenpt_BR
dc.publisherSociedade Brasileira de Químicapt_BR
dc.rightsAcesso Abertopt_BR
dc.titleSynthesis and expansion of bicyclic enol ether: a probable precursor for the synthesis of macrolide (±)-pyrenophorinpt_BR
dc.typeArtigopt_BR
dc.subject.keywordQuímica orgânicapt_BR
dc.subject.keywordAntibióticospt_BR
dc.rights.license(CC BY) - This is an open-access article distributed under the terms of the Creative Commons Attribution License.-
dc.identifier.doihttp://dx.doi.org/10.21577/0103-5053.20170114pt_BR
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