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Title: Raman spectroscopy as a powerful technique in the characterization of ferrofluids
Authors: Sousa, Marcelo Henrique
Rubim, Joel Camargo
Silva, Jean Clay de Oliveira e
Tourinho, Francisco Augusto
Assunto:: Análise espectral
Espectroscopia de Raman
Espectroscopia
Issue Date: Sep-2001
Publisher: Sociedade Brasileira de Física
Citation: SOUSA, Marcelo Henrique et al. Raman spectroscopy as a powerful technique in the characterization of ferrofluids. Brazilian Journal of Physics, São Paulo, v. 31, n. 3, set. 2001. Disponível em: <http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-97332001000300010&lng=pt&nrm=iso>. Acesso em: 14 nov 2012. http://dx.doi.org/10.1590/S0103-97332001000300010.
Abstract: Raman spectroscopy has been used to get some insight into the chemical composition and structure of magnetic fluids based on ferrites. The inner as well as the surface structure of Fe-maghemite and Zn-maghemite have characterized by Raman spectroscopy. It has been shown that different chemical species are present on the maghemite surface by changing the laser excitation energy. Maghemites modified by the adsorption of aspartic and glutamic acids as well as those modified by the adsorption of methylene blue(MB) have also been investigated by Raman spectroscopy. It has been shown that while FTIR (Fourier transform infrared) spectroscopy gives almost no information regarding to the surface species, Raman spectroscopy in and off resonance gives suitable information regarding to the adsorbate structure and bonding. The Raman spectroscopy study of the modified maghemites have shown that the organic acids adsorb on the maghemite surfarce as glutamate and aspartate chemically bounded to Fe(III) ions on the maghemite surface, and that MB, a cation, adsorbs on the maghemite surface as a monomer by ion pair formation with coadsorbed nitrate.
Licença:: Brazilian Journal of Physics - Todo o conteúdo deste periódico, exceto onde está identificado, está licenciado sob uma Licença Creative Common (Attribution-NonCommercial 3.0 Unported (CC BY-NC 3.0)). Fonte: http://www.scielo.br/scielo.php?script=sci_serial&pid=0103-9733&lng=pt&nrm=iso. Acesso em: 14 nov. 2012.
DOI: http://dx.doi.org/10.1590/S0103-97332001000300010
Appears in Collections:FCE-FAR - Artigos publicados em periódicos
IQ - Artigos publicados em periódicos

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